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TERS has been successfully applied to the study of polymer-blends revealing numerous novel insights. Nanoscale probing of the surface composition of a polystyrene-polyisoprene (PS-PI) blend film with AFM-TERS was carried out by Yeo et al. [ 56 ]. In this study, TERS was used to study polymers with low Raman scattering cross sections for the first time. The authors identified PI and PS at the surface and sub-surface, respectively and discovered the presence of sub-surface nanopores in the PS film; these results couldnât be obtained using other characterisation techniques. However, only individual TERS spectra from different locations on the surface of the polymer blend were obtained in this work.